Most males do stop spraying after they are fixed. The occasional one may not, it depends often on their age at the time of neuter. Obviously the younger they are neutered the better.Yes he will stop...
While it's true that the vast majority of male cats do stop spraying after being neutered, it's not an iron clad guarantee. The intact male cat sprays not only to mark his territory, but also to attract female cats in heat for mating, and this seems to particularly be true with outdoor cats. Since neutering cats tend to not want to go outside as much after being fixed, and if you have no other cats in your house that may cause territorial issues, chances are very good the neutering procedure will eliminate the spraying tendencies completely. This has been 100% true in all three of the male cats I've had neutered.Most cats do stop spraying after being neutered. I rescued an adult tom cat from the pound and he sprayed as soon as I got him home. He was neutered the next morning and never sprayed again (even in a house with several strange cats, all of whom were fixed). The testosterone will stay in his system for about a month after neutering and until it's gone, he will think he's still a tom cat and may continue to spray for awhile. You might want to keep him in an easy to clean room till you're sure he's stopped. Like I said, most stop immediately after neuter, but there's no guarantee he will. It's worth a shot though. He deserves a second chance at a good life.
Use of a Feliway diffuser or spray can help with his transition and curb his desire to spray. I've used the diffuser for issues other than marking and have had good results with it. Here's more about it.
http://www.feliway.com/gb/How-Feliway-R-can-help/How-do-I-use-Feliway-R/Urine-Marking
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